Europium(II) fluoride

Names
IUPAC name Europium(II) fluoride
Other names Europium difluoride
Identifiers
CAS Number	14077-39-5 Y
3D model (JSmol)	Interactive image Interactive image
ChemSpider	13834724
ECHA InfoCard	100.203.721
PubChem CID	21225127
CompTox Dashboard (EPA)	DTXSID00611473
InChI InChI=1S/Eu.2FH/h;2*1H/q+2;;/p-2 Key: YLDGIMHVWSTRML-UHFFFAOYSA-L
SMILES F[Eu]F [F-].[F-].[Eu+2]
Properties
Chemical formula	EuF2
Molar mass	189.96
Appearance	dark yellowish solid[1]
Density	6.495 g·cm−3
Structure[2]
Crystal structure	Fluorite structure
Space group	Fm3m (No. 225)
Lattice constant	a = 584.23 pm
Formula units (Z)	4
Hazards
GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H301
Precautionary statements	P264, P270, P301+P310, P321, P330, P405, P501
Related compounds
Other anions	Europium(II) bromide Europium(II) chloride Europium(II) iodide
Other cations	Samarium(II) fluoride Thulium(II) fluoride Ytterbium(II) fluoride
Related compounds	Europium(III) fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Europium(II) fluoride is an inorganic compound with a chemical formula EuF₂. It was first synthesized in 1937.^[1]

Production

Europium(II) fluoride can be produced by reducing europium(III) fluoride with metallic europium or hydrogen gas.^[3]

${\displaystyle \mathrm {2\ EuF_{3}+Eu\longrightarrow 3\ EuF_{2}} }$

${\displaystyle \mathrm {2\ EuF_{3}+H_{2}\longrightarrow 2\ EuF_{2}+2\ HF} }$

Properties

Europium(II) fluoride is a bright yellowish solid with a fluorite structure.^[3]

EuF₂ can be used to dope a trivalent rare-earth fluoride, such as LaF₃, to create a vacancy-filled structure with increased conductivity over a pure crystal. Such a crystal can be used as a fluoride-specific semipermeable membrane in a fluoride selective electrode to detect trace quantities of fluoride.^[4][5]

References